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Issue 21, 2011
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Influence of charge repulsion on binding strengths: experimental and computational characterization of mixed alkali metal complexes of decamethylcucurbit[5]uril in the gas phase

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Abstract

Theory and experiment demonstrate that Coulombic repulsion plays a dominant role in the strength of binding a second cation to a rigid, ditopic host.

Graphical abstract: Influence of charge repulsion on binding strengths: experimental and computational characterization of mixed alkali metal complexes of decamethylcucurbit[5]uril in the gas phase

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Publication details

The article was received on 24 Feb 2011, accepted on 23 Mar 2011 and first published on 11 Apr 2011


Article type: Communication
DOI: 10.1039/C1CC11090J
Citation: Chem. Commun., 2011,47, 6081-6083
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    Influence of charge repulsion on binding strengths: experimental and computational characterization of mixed alkali metal complexes of decamethylcucurbit[5]uril in the gas phase

    D. N. Mortensen and D. V. Dearden, Chem. Commun., 2011, 47, 6081
    DOI: 10.1039/C1CC11090J

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