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Issue 18, 2011
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Side chain Co(I) polymers featuring acrylate functionalized neutral 18 electron CpCo(C4R4) (R = Ph, Me) units

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Abstract

The synthesis of novel Co(I) polymers featuring CpCo(C4R4) units are reported. The cyclopentadienyl ring on the CpCo(C4R4) unit has been functionalized with acrylate or methacrylate groups. Acrylate derivatives of these compounds were found to polymerize giving rise to the first example of polymers containing neutral, 18 e cobaltoarenocenes in the side chain.

Graphical abstract: Side chain Co(i) polymers featuring acrylate functionalized neutral 18 electron CpCo(C4R4) (R = Ph, Me) units

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Publication details

The article was received on 23 Feb 2011, accepted on 17 Mar 2011 and first published on 31 Mar 2011


Article type: Communication
DOI: 10.1039/C1CC11076D
Citation: Chem. Commun., 2011,47, 5301-5303
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    Side chain Co(I) polymers featuring acrylate functionalized neutral 18 electron CpCo(C4R4) (R = Ph, Me) units

    P. Chadha and P. J. Ragogna, Chem. Commun., 2011, 47, 5301
    DOI: 10.1039/C1CC11076D

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