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Issue 18, 2011
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Copper-mediated methylthiolation of aryl halides with DMSO

Fang Luo,a  Changduo Pan,b  Liping Li,a  Fan Chen*a  and  Jiang Cheng*a 
Author affiliations

* Corresponding authors

a College of Chemistry & Materials Engineering, Wenzhou University, Wenzhou 325000, People's Republic of China
E-mail: jiangcheng@wzu.edu.cn, fanchen@wzu.edu.cn

b Wenzhou Institute of Industry & Science, Wenzhou 325000, People's Republic of China

Abstract

A copper-mediated methylthiolation of aryl halides with the widely available DMSO is described. The procedure tolerates a series of functional groups such as methoxy, nitro, chloro, fluoro, trifluoromethyl, formyl and methoxycarbonyl groups. Thus, it represents a simple and facile methylthiolation procedure.

Graphical abstract: Copper-mediated methylthiolation of aryl halides with DMSO

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Publication details

The article was received on 11 Feb 2011, accepted on 17 Mar 2011 and first published on 31 Mar 2011


Article type: Communication
DOI: 10.1039/C1CC10795J
Citation: Chem. Commun., 2011,47, 5304-5306
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    Copper-mediated methylthiolation of aryl halides with DMSO

    F. Luo, C. Pan, L. Li, F. Chen and J. Cheng, Chem. Commun., 2011, 47, 5304
    DOI: 10.1039/C1CC10795J

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