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Issue 22, 2011
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Novel rhenium(I) catalysts for the isomerization of propargylic alcohols into α,β-unsaturated carbonyl compounds: an unprecedented recyclable catalytic system in ionic liquids

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Abstract

Carbonyl rhenium(I) complexes are efficient catalysts for the regioselective isomerization of terminal propargylic alcohols into α,β-unsaturated aldehydes or ketones which can be used as an unprecedented recyclable catalytic system (up to 10 consecutive runs) in the ionic liquid [BMIM][PF6].

Graphical abstract: Novel rhenium(i) catalysts for the isomerization of propargylic alcohols into α,β-unsaturated carbonyl compounds: an unprecedented recyclable catalytic system in ionic liquids

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Publication details

The article was received on 09 Feb 2011, accepted on 14 Apr 2011 and first published on 09 May 2011


Article type: Communication
DOI: 10.1039/C1CC10768B
Citation: Chem. Commun., 2011,47, 6470-6472
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    Novel rhenium(I) catalysts for the isomerization of propargylic alcohols into α,β-unsaturated carbonyl compounds: an unprecedented recyclable catalytic system in ionic liquids

    J. García-Álvarez, J. Díez, J. Gimeno and C. M. Seifried, Chem. Commun., 2011, 47, 6470
    DOI: 10.1039/C1CC10768B

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