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Issue 18, 2011
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Frontal polymerizations carried out in deep-eutectic mixtures providing both the monomers and the polymerization medium

Josué D. Mota-Morales,ab  María C. Gutiérrez,b  Isaac C. Sanchez,c  Gabriel Luna-Bárcenas*a  and  Francisco del Monte*b 
Author affiliations

* Corresponding authors

a Centro de Investigación y Estudios Avanzados (CINVESTAV) Unidad Querétaro, Libramiento Norponiente 2000, Querétaro, QRO., México
E-mail: gluna@qro.cinvestav.mx
Fax: +52 4422119939
Tel: +52 4422119900

b Instituto de Ciencia de Materiales de Madrid (ICMM), Consejo Superior de Investigaciones Científicas (CSIC), Cantoblanco 28049, Spain
E-mail: delmonte@icmm.csic.es
Fax: +34 913720623
Tel: +34 913349033

c Department of Chemical Engineering, The University of Texas at Austin, Austin, USA

Abstract

Deep Eutectic Solvents (DESs) based upon mixtures of Acrylic Acid (AA) or Methacrylic Acid (MAA) and Choline Chloride (CCl) demonstrated superior performance than regular organic solvents and even ionic liquids for frontal polymerizations (FPs). Full recovering of CCl after FP provided an interesting green character to the process.

Graphical abstract: Frontal polymerizations carried out in deep-eutectic mixtures providing both the monomers and the polymerization medium

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Publication details

The article was received on 20 Jan 2011, accepted on 18 Mar 2011 and first published on 01 Apr 2011


Article type: Communication
DOI: 10.1039/C1CC10391A
Citation: Chem. Commun., 2011,47, 5328-5330
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    Frontal polymerizations carried out in deep-eutectic mixtures providing both the monomers and the polymerization medium

    J. D. Mota-Morales, M. C. Gutiérrez, I. C. Sanchez, G. Luna-Bárcenas and F. del Monte, Chem. Commun., 2011, 47, 5328
    DOI: 10.1039/C1CC10391A

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