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Issue 16, 2011
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Direct synthesis of ester-containing indium homoenolate and its application in palladium-catalyzed cross-coupling with aryl halide

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Abstract

An efficient method for the synthesis of ester-containing indium homoenolatevia a direct insertion of indium into β-halo ester in the presence of CuI/LiCl was described. The synthetic utility of the indium homoenolate was demonstrated by palladium-catalyzed cross-coupling with aryl halides in DMA with wide functional group compatibility.

Graphical abstract: Direct synthesis of ester-containing indium homoenolate and its application in palladium-catalyzed cross-coupling with aryl halide

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Publication details

The article was received on 15 Dec 2010, accepted on 22 Feb 2011 and first published on 17 Mar 2011


Article type: Communication
DOI: 10.1039/C0CC05597B
Citation: Chem. Commun., 2011,47, 4778-4780
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    Direct synthesis of ester-containing indium homoenolate and its application in palladium-catalyzed cross-coupling with aryl halide

    Z. Shen, K. K. K. Goh, C. H. A. Wong, Y. Yang, Y. Lai, H. Cheong and T. Loh, Chem. Commun., 2011, 47, 4778
    DOI: 10.1039/C0CC05597B

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