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Issue 13, 2011
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Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

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Abstract

Efficient catalysts for the dehydrocoupling or dehydropolymerisation of H3B·NMexH(3−x) (x = 1, 2) have been developed by variation of the P–Rh–P angle in {Rh(Ph2P(CH2)nPPh2)}+ fragments (n = 2–5).

Graphical abstract: Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

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Publication details

The article was received on 08 Dec 2010, accepted on 20 Jan 2011 and first published on 03 Feb 2011


Article type: Communication
DOI: 10.1039/C0CC05460G
Citation: Chem. Commun., 2011,47, 3763-3765
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    Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

    R. Dallanegra, A. P. M. Robertson, A. B. Chaplin, I. Manners and A. S. Weller, Chem. Commun., 2011, 47, 3763
    DOI: 10.1039/C0CC05460G

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