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Issue 10, 2011
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A well-defined silica-supported aluminium alkyl through an unprecedented, consecutive two-step protonolysis–alkyl transfer mechanism

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Abstract

Impregnation of [(AliBu3)(Et2O)] on partially dehydroxylated SBA-15 affords a mesoporous material bearing the well-defined single site surface aluminium species [([triple bond, length as m-dash]SiO)2Al(iBu)(Et2O)].

Graphical abstract: A well-defined silica-supported aluminium alkyl through an unprecedented, consecutive two-step protonolysis–alkyl transfer mechanism

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Publication details

The article was received on 16 Nov 2010, accepted on 06 Jan 2011 and first published on 21 Jan 2011


Article type: Communication
DOI: 10.1039/C0CC04986G
Citation: Chem. Commun., 2011,47, 2979-2981
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    A well-defined silica-supported aluminium alkyl through an unprecedented, consecutive two-step protonolysis–alkyl transfer mechanism

    J. Pelletier, J. Espinas, N. Vu, S. Norsic, A. Baudouin, L. Delevoye, J. Trébosc, E. Le Roux, C. Santini, J. Basset, R. M. Gauvin and M. Taoufik, Chem. Commun., 2011, 47, 2979
    DOI: 10.1039/C0CC04986G

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