Jump to main content
Jump to site search

Issue 8, 2011
Previous Article Next Article

Towards energetically viable asymmetric deprotonations: selectivity at more elevated temperatures with C2-symmetric magnesium bisamides

Author affiliations

Abstract

A novel chiral magnesium bisamide has enabled the development of effective asymmetric deprotonation protocols at substantially more elevated temperatures. This new, structurally simple, C2-symmetric magnesium complex displays excellent levels of asymmetric efficiency and energy reduction in the synthesis of enantioenriched enol silanes.

Graphical abstract: Towards energetically viable asymmetric deprotonations: selectivity at more elevated temperatures with C2-symmetric magnesium bisamides

Back to tab navigation

Supplementary files

Publication details

The article was received on 12 Nov 2010, accepted on 22 Dec 2010 and first published on 18 Jan 2011


Article type: Communication
DOI: 10.1039/C0CC04939E
Citation: Chem. Commun., 2011,47, 2264-2266
  •   Request permissions

    Towards energetically viable asymmetric deprotonations: selectivity at more elevated temperatures with C2-symmetric magnesium bisamides

    L. S. Bennie, W. J. Kerr, M. Middleditch and A. J. B. Watson, Chem. Commun., 2011, 47, 2264
    DOI: 10.1039/C0CC04939E

Search articles by author

Spotlight

Advertisements