Issue 4, 2011
From the journal:

Chemical Communications

On/off luminescence vapochromic selective sensing of benzene and its methylated derivatives by a trinuclear silver(i) pyrazolate sensor†

Manal A. Rawashdeh-Omary,*a   Maher D. Rashdan,a   Shylaja Dharanipathi,a   Oussama Elbjeirami,‡a   Prashanth Rameshb  and  H. V. Rasika Dias*b  

* Corresponding authors

a Department of Chemistry and Physics, Texas Woman's University, Denton, Texas, USA
E-mail: momary@twu.edu

b Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, Texas, USA
E-mail: dias@uta.edu

Abstract

{[3,5-(CF3)2Pz]Ag}3 (1) films exhibit selective/reversible sensing of small-organic-molecule (SAM) vapors, which readily switch-on bright-green (benzene or toluene) or bright-blue (mesitylene) luminescence that switches-off upon vapor removal. Vapors of electron-deficient SAMs or non-aromatic solvents did not attain luminescence switching and were not adsorbed.

Graphical abstract: On/off luminescence vapochromic selective sensing of benzene and its methylated derivatives by a trinuclear silver(i) pyrazolate sensor

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Article information

DOI
https://doi.org/10.1039/C0CC03964K
Article type
Communication
Submitted
19 Sep 2010
Accepted
18 Oct 2010
First published
17 Nov 2010

Chem. Commun., 2011,47, 1160-1162

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On/off luminescence vapochromic selective sensing of benzene and its methylated derivatives by a trinuclear silver(I) pyrazolate sensor

M. A. Rawashdeh-Omary, M. D. Rashdan, S. Dharanipathi, O. Elbjeirami, P. Ramesh and H. V. R. Dias, Chem. Commun., 2011, 47, 1160 DOI: 10.1039/C0CC03964K

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