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Issue 43, 2011
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Pyridine synthesis from oximes and alkynesviarhodium(III) catalysis: Cp* and Cpt provide complementary selectivity

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Abstract

The synthesis of pyridines from readily available α,β-unsaturated oximes and alkynes under mild conditions and low temperatures using Rh(III) catalysis has been developed. It was found that the use of sterically different ligands allows for complementary selectivities to be achieved.

Graphical abstract: Pyridine synthesis from oximes and alkynesviarhodium(iii) catalysis: Cp* and Cpt provide complementary selectivity

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Publication details

The article was received on 23 Aug 2011, accepted on 21 Sep 2011 and first published on 10 Oct 2011


Article type: Communication
DOI: 10.1039/C1CC15248C
Citation: Chem. Commun., 2011,47, 11846-11848
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    Pyridine synthesis from oximes and alkynesviarhodium(III) catalysis: Cp* and Cpt provide complementary selectivity

    T. K. Hyster and T. Rovis, Chem. Commun., 2011, 47, 11846
    DOI: 10.1039/C1CC15248C

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