Issue 42, 2011
From the journal:

Chemical Communications

Protic ionic liquids based on phosphonium cations: comparison with ammonium analogues†

Usman Ali Rana,*a   R. Vijayaraghavan,b   Mareike Walther,c   Jiazeng Sun,ab   Angel A. J. Torriero,d   Maria Forsythd  and  Douglas R. MacFarlaneb  

* Corresponding authors

a Materials Engineering Department, Monash University, Clayton VIC, Australia
E-mail: usmanali.rana@monash.edu

b School of Chemistry, Monash University, Clayton VIC, Australia

c Universität Leipzig, Institut für Anorganische Chemie, Johannisallee 29, 04103 Leipzig, Germany

d Department of Materials Engineering, Deakin Univeristy, Australia

Abstract

Novel protic ionic liquids (PILs) based on a tributyl phosphonium cation have been synthesised and characterised, revealing that the phosphonium based ILs show high thermal stability, high ionic conductivity and facile proton reduction compared to the corresponding ammonium based ILs.

Graphical abstract: Protic ionic liquids based on phosphonium cations: comparison with ammonium analogues

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Article information

DOI
https://doi.org/10.1039/C1CC14761G
Article type
Communication
Submitted
02 Aug 2011
Accepted
22 Sep 2011
First published
30 Sep 2011

Chem. Commun., 2011,47, 11612-11614

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Protic ionic liquids based on phosphonium cations: comparison with ammonium analogues

U. A. Rana, R. Vijayaraghavan, M. Walther, J. Sun, A. A. J. Torriero, M. Forsyth and D. R. MacFarlane, Chem. Commun., 2011, 47, 11612 DOI: 10.1039/C1CC14761G

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