Issue 38, 2011
From the journal:

Chemical Communications

Reverse orthogonal strategy for oligosaccharide synthesis†‡§

Kohki Fujikawa,a   N. Vijaya Ganesh,a   Yih Horng Tan,a   Keith J. Stinea  and  Alexei V. Demchenko*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Missouri–St. Louis, One University Boulevard, St. Louis, Missouri 63121, USA
E-mail: demchenkoa@umsl.edu

Abstract

Herein, we report the invention of a novel expeditious concept for oligosaccharide synthesis. Unlike the classic orthogonal strategy based on leaving groups, the reverse approach is based on orthogonal protecting groups, herein p-methoxybenzyl and 4-pentenoyl, which allows for efficient oligosaccharide assembly in the reverse direction.

Graphical abstract: Reverse orthogonal strategy for oligosaccharide synthesis

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Article information

DOI
https://doi.org/10.1039/C1CC13409D
Article type
Communication
Submitted
09 Jun 2011
Accepted
16 Aug 2011
First published
05 Sep 2011

Chem. Commun., 2011,47, 10602-10604

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Reverse orthogonal strategy for oligosaccharide synthesis

K. Fujikawa, N. V. Ganesh, Y. H. Tan, K. J. Stine and A. V. Demchenko, Chem. Commun., 2011, 47, 10602 DOI: 10.1039/C1CC13409D

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