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Issue 17, 2011
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Titanium alkoxyimido (Ti<img border='0' src='http://www.rsc.org/images/entities/h2_char_e001.gif' alt='[double bond, length as m-dash]'/>N–OR) complexes: reductive N–O bond cleavage at the boundary between hydrazide and peroxide ligands

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Abstract

The first Group 4 alkoxyimido compounds are reported. The Ti[double bond, length as m-dash]N–OtBu group in Ti(N2NMe)(NOtBu)(py) undergoes facile 2-electron N–O bond cleavage with PhCCMe as the reductant to form a 1,2-diamidoalkene groupvia two highly selective N–C bond forming events.

Graphical abstract: Titanium alkoxyimido (Ti<img border='0' src='http://www.rsc.org/images/entities/char_e001.gif' alt='[double bond, length as m-dash]'/>N–OR) complexes: reductive N–O bond cleavage at the boundary between hydrazide and peroxide ligands

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Publication details

The article was received on 14 Feb 2011, accepted on 14 Mar 2011 and first published on 28 Mar 2011


Article type: Communication
DOI: 10.1039/C1CC10862J
Citation: Chem. Commun., 2011,47, 4926-4928
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    Titanium alkoxyimido (Ti<img border='0' src='http://www.rsc.org/images/entities/h2_char_e001.gif' alt='[double bond, length as m-dash]'/>N–OR) complexes: reductive N–O bond cleavage at the boundary between hydrazide and peroxide ligands

    A. D. Schwarz, A. Nova, E. Clot and P. Mountford, Chem. Commun., 2011, 47, 4926
    DOI: 10.1039/C1CC10862J

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