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Department of Chemistry, Brandeis University, 415 South Street, Waltham, USA
E-mail: thomasc@brandeis.edu
; Fax: +1 781-736-2516
; Tel: +1 781-736-2576
Chem. Commun., 2011,47, 3634-3636
DOI:
10.1039/C0CC05739H
Received
22 Dec 2010,
Accepted
28 Jan 2011
First published online
10 Feb 2011
The synthesis of a new pincer ligand containing a central cationic N-heterocyclic phosphenium donor is described. The electrophilic nature of this cationic ligand renders it non-innocent, and coordination of this ligand to a PtCl2 fragment leads to chloride migration from Pt to the cationic phosphorus center.
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