Restricted rotation due to the lack of free space within a capsule translates into product selectivity: photochemistry of cyclohexyl phenyl ketones within a water-soluble organic capsule

Revathy Kulasekharan; Rajib Choudhury; Rajeev Prabhakar; V. Ramamurthy

doi:10.1039/C0CC05337F

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Restricted rotation due to the lack of free space within a capsule translates into product selectivity: photochemistry of cyclohexyl phenyl ketones within a water-soluble organic capsule†‡

Revathy Kulasekharan,^a Rajib Choudhury,^a Rajeev Prabhakar^a and V. Ramamurthy*^a

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^a Department of Chemistry, University of Miami, Coral Gables, FL, USA
E-mail: murthy1@miami.edu
Tel: +1 305 284 1534

Abstract

The rotational mobility of organic guest molecules when included within a confined capsule is restricted and this feature could be translated into product selectivity as established with the photochemical behavior of cyclohexyl phenyl ketones.

This article is part of the themed collection: Supramolecular Chemistry

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Article information

DOI: https://doi.org/10.1039/C0CC05337F
Article type: Communication
Submitted: 02 Dec 2010
Accepted: 06 Jan 2011
First published: 21 Jan 2011

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Chem. Commun., 2011,47, 2841-2843

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Restricted rotation due to the lack of free space within a capsule translates into product selectivity: photochemistry of cyclohexyl phenyl ketones within a water-soluble organic capsule

R. Kulasekharan, R. Choudhury, R. Prabhakar and V. Ramamurthy, Chem. Commun., 2011, 47, 2841 DOI: 10.1039/C0CC05337F

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Chemical Communications

Restricted rotation due to the lack of free space within a capsule translates into product selectivity: photochemistry of cyclohexyl phenyl ketones within a water-soluble organic capsule†‡

Abstract

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Restricted rotation due to the lack of free space within a capsule translates into product selectivity: photochemistry of cyclohexyl phenyl ketones within a water-soluble organic capsule

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