Issue 10, 2011
From the journal:

Chemical Communications

Restricted rotation due to the lack of free space within a capsule translates into product selectivity: photochemistry of cyclohexyl phenyl ketones within a water-soluble organic capsule†‡

Revathy Kulasekharan,a   Rajib Choudhury,a   Rajeev Prabhakara  and  V. Ramamurthy*a  

* Corresponding authors

a Department of Chemistry, University of Miami, Coral Gables, FL, USA
E-mail: murthy1@miami.edu
Tel: +1 305 284 1534

Abstract

The rotational mobility of organic guest molecules when included within a confined capsule is restricted and this feature could be translated into product selectivity as established with the photochemical behavior of cyclohexyl phenyl ketones.

Graphical abstract: Restricted rotation due to the lack of free space within a capsule translates into product selectivity: photochemistry of cyclohexyl phenyl ketones within a water-soluble organic capsule

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Article information

DOI
https://doi.org/10.1039/C0CC05337F
Article type
Communication
Submitted
02 Dec 2010
Accepted
06 Jan 2011
First published
21 Jan 2011

Chem. Commun., 2011,47, 2841-2843

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Restricted rotation due to the lack of free space within a capsule translates into product selectivity: photochemistry of cyclohexyl phenyl ketones within a water-soluble organic capsule

R. Kulasekharan, R. Choudhury, R. Prabhakar and V. Ramamurthy, Chem. Commun., 2011, 47, 2841 DOI: 10.1039/C0CC05337F

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