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The TiNNMe2group of Cp*Ti{MeC(NiPr)2}(NNMe2) undergoes 1,2-addition with Si–Cl and reversible addition with Si–H bonds of RSiH2X (R = Ph or Bu; X = Cl or H). Labeling studies show that the so-formed silylhydrazide–hydride products react with primary silanes or H2via σ-bond metathesis between Ti–H and either Si–H or H–H.
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