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Issue 2, 2011
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New synthesis of meso-free-[14]triphyrin(2.1.1) by McMurry coupling and its derivatization to Mn(I) and Re(I) complexes

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Abstract

The metal-free and meso-free [14]triphyrin(2.1.1) compound was successfully prepared based on the intramolecular McMurry coupling reaction of diformyl-tripyrrane in 16% yield, and was converted to the bowl-shaped Mn(I)(TriP)(CO)3 and Re(I)(TriP)(CO)3.

Graphical abstract: New synthesis of meso-free-[14]triphyrin(2.1.1) by McMurry coupling and its derivatization to Mn(i) and Re(i) complexes

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Publication details

The article was received on 08 Oct 2010, accepted on 29 Oct 2010 and first published on 16 Nov 2010


Article type: Communication
DOI: 10.1039/C0CC04286B
Citation: Chem. Commun., 2011,47, 722-724
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    New synthesis of meso-free-[14]triphyrin(2.1.1) by McMurry coupling and its derivatization to Mn(I) and Re(I) complexes

    D. Kuzuhara, H. Yamada, Z. Xue, T. Okujima, S. Mori, Z. Shen and H. Uno, Chem. Commun., 2011, 47, 722
    DOI: 10.1039/C0CC04286B

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