Issue 2, 2011

Temperature dependent selective gas sorption of the microporous metal-imidazolate framework [Cu(L)] [H2L = 1,4-di(1H-imidazol-4-yl)benzene]

Abstract

A highly stable copper(II) microporous framework with cylindrical channels constructed from 1,4-di(1H-imidazol-4-yl)benzene (H2L) and CuCl2·2H2O is composed of Cu(II)-imidazolate tubes interconnected by the 1,4-phenylene group of L2−, and shows temperature dependent selective gas sorption properties.

Graphical abstract: Temperature dependent selective gas sorption of the microporous metal-imidazolate framework [Cu(L)] [H2L = 1,4-di(1H-imidazol-4-yl)benzene]

Supplementary files

Article information

Article type
Communication
Submitted
26 Sep 2010
Accepted
08 Oct 2010
First published
11 Nov 2010

Chem. Commun., 2011,47, 752-754

Temperature dependent selective gas sorption of the microporous metal-imidazolate framework [Cu(L)] [H2L = 1,4-di(1H-imidazol-4-yl)benzene]

S. Chen, M. Chen, S. Takamizawa, M. Chen, Z. Su and W. Sun, Chem. Commun., 2011, 47, 752 DOI: 10.1039/C0CC04085A

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