Issue 9, 2011
From the journal:

Chemical Communications

2D flexible metal–organic frameworks with [Cd2(μ2-X)2](X = Cl or Br) units exhibiting selective fluorescence sensing for small molecules†

Xu-Hui Jin,a   Jian-Ke Sun,a   Li-Xuan Caia  and  Jie Zhang*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter and Graduate School of the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: zhangjie@fjirsm.ac.cn
Fax: +86 591-83710051

Abstract

Two isomorphous 2D flexible metal–organic frameworks with [Cd2(μ2-X)2] (X = Cl or Br) units and dynamic 1D channels, which show tunable or switchable fluorescence signals in response to the loss of guest water molecules, have been synthesized and characterized. Especially, the chloride-bridged complex is found to be a selective fluorescence sensor for MeCN.

Graphical abstract: 2D flexible metal–organic frameworks with [Cd2(μ2-X)2](X = Cl or Br) units exhibiting selective fluorescence sensing for small molecules

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Article information

DOI
https://doi.org/10.1039/C0CC04084C
Article type
Communication
Submitted
26 Sep 2010
Accepted
13 Dec 2010
First published
12 Jan 2011

Chem. Commun., 2011,47, 2667-2669

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2D flexible metal–organic frameworks with [Cd2(μ2-X)2](X = Cl or Br) units exhibiting selective fluorescence sensing for small molecules

X. Jin, J. Sun, L. Cai and J. Zhang, Chem. Commun., 2011, 47, 2667 DOI: 10.1039/C0CC04084C

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