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Issue 5, 2011
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Heterobimetallic rhodium–gold halide and hydride complexes

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Abstract

Heterobimetallic RhIAuIhalide complexes react with LiHBEt3 to afford the corresponding hydride, and they are oxidised by halogen to afford thermally stable RhIIAuII complexes. The hydride complex reacts with acid and halogen sources to produce H2 and HCl, respectively. The RhIIAuII complexes exhibit optical and photochemical properties that are derived from the bimetallic core.

Graphical abstract: Heterobimetallic rhodium–gold halide and hydride complexes

  • This article is part of the themed collection: Hydrogen
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Publication details

The article was received on 14 Aug 2010, accepted on 18 Nov 2010 and first published on 06 Dec 2010


Article type: Communication
DOI: 10.1039/C0CC03261A
Citation: Chem. Commun., 2011,47, 1485-1487
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    Heterobimetallic rhodium–gold halide and hydride complexes

    T. S. Teets, M. P. Neumann and D. G. Nocera, Chem. Commun., 2011, 47, 1485
    DOI: 10.1039/C0CC03261A

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