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Issue 3, 2011
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Palladium catalyzed carboxylation of allylstannanes and boranes using CO2

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Abstract

A family of well-defined (η3-allyl)Pd(L)(carboxylate) (L = PR3 or NHC) complexes are by far the most efficient catalysts reported to date for the catalytic carboxylation of allylstannanes into allylcarboxylates using CO2. The substrate scope of this reaction is extended to both substituted allylstannanes and allylboranes.

Graphical abstract: Palladium catalyzed carboxylation of allylstannanes and boranes using CO2

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Publication details

The article was received on 11 Aug 2010, accepted on 27 Oct 2010 and first published on 15 Nov 2010


Article type: Communication
DOI: 10.1039/C0CC03191G
Citation: Chem. Commun., 2011,47, 1069-1071
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    Palladium catalyzed carboxylation of allylstannanes and boranes using CO2

    J. Wu and N. Hazari, Chem. Commun., 2011, 47, 1069
    DOI: 10.1039/C0CC03191G

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