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Issue 1, 2011
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Site-specific introduction of gold-carbenoids by intermolecular oxidation of ynamides or ynol ethers

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Abstract

Ynamides and ynol ethers undergo intermolecular gold-catalysed reaction with a nucleophilic oxidant to access metal-carbenoid reactivity patterns. A site-specific oxidation/1,2-insertion cascade is used for a general access to functionalised α,β-unsaturated carboxylic acid derivatives and vinylogous carbimates.

Graphical abstract: Site-specific introduction of gold-carbenoids by intermolecular oxidation of ynamides or ynol ethers

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Publication details

The article was received on 22 Jul 2010, accepted on 17 Aug 2010 and first published on 08 Sep 2010


Article type: Communication
DOI: 10.1039/C0CC02736G
Citation: Chem. Commun., 2011,47, 379-381
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    Site-specific introduction of gold-carbenoids by intermolecular oxidation of ynamides or ynol ethers

    P. W. Davies, A. Cremonesi and N. Martin, Chem. Commun., 2011, 47, 379
    DOI: 10.1039/C0CC02736G

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