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Issue 1, 2011
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Double addition of H2 to transition metal–borane complexes: a ‘hydride shuttle’ process between boron and transition metal centres

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Abstract

The addition of H2 across a transition metal–borane bond is reported for the first time providing a mechanism for recharging borane functional groups to borohydride.

Graphical abstract: Double addition of H2 to transition metal–borane complexes: a ‘hydride shuttle’ process between boron and transition metal centres

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Publication details

The article was received on 30 Jun 2010, accepted on 23 Sep 2010 and first published on 11 Oct 2010


Article type: Communication
DOI: 10.1039/C0CC02245D
Citation: Chem. Commun., 2011,47, 484-486
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    Double addition of H2 to transition metal–borane complexes: a ‘hydride shuttle’ process between boron and transition metal centres

    N. Tsoureas, Y. Kuo, M. F. Haddow and G. R. Owen, Chem. Commun., 2011, 47, 484
    DOI: 10.1039/C0CC02245D

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