Issue 1, 2011
From the journal:

Chemical Communications

Brønsted acid differentiated metal catalysis by kinetic discrimination†‡

Magnus Rueping*a  and  René M. Koenigsa  

* Corresponding authors

a RWTH Aachen University, Institute of Organic Chemistry, Landoltweg 1, D-52074 Aachen, Germany
E-mail: magnus.rueping@rwth-aachen.de
Fax: +49 241 8092665

Abstract

A Brønsted acid differentiated metal catalyzed hydrogenation has been developed. A combinatorial variation of chiral triflylamides with achiral metal complexes results in a highly active catalyst for the asymmetric reduction.

Graphical abstract: Brønsted acid differentiated metal catalysis by kinetic discrimination

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Article information

DOI
https://doi.org/10.1039/C0CC02167A
Article type
Communication
Submitted
28 Jun 2010
Accepted
26 Jul 2010
First published
17 Aug 2010

Chem. Commun., 2011,47, 304-306

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Brønsted acid differentiated metal catalysis by kinetic discrimination

M. Rueping and R. M. Koenigs, Chem. Commun., 2011, 47, 304 DOI: 10.1039/C0CC02167A

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