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Issue 4, 2011
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Oxidation of benzylic compounds by gold nanowires at 1 atm O2

Lei Hu,a  Xueqin Cao,a  Jianhui Yang,b  Min Li,a  Haiyan Hong,a  Qingfeng Xu,a  Jianfeng Ge,a  Lihua Wang,a  Jianmei Lu,*a  Liang Chen*b  and  Hongwei Gu*a 
Author affiliations

* Corresponding authors

a Key Laboratory of Organic Synthesis of Jiangsu Province, Key Laboratory of Absorbent Materials and Techniques for Environment, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, China
E-mail: lujm@suda.edu.cn, hongwei@suda.edu.cn
Fax: +86-65880905
Tel: +86-65880905

b Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo, China

Abstract

Ultra-thin gold nanowires (GNWs), with uniform surface crystallinity, appear much more active than gold nanoclusters in benzylic compound oxidation. Ethylbenzene oxidation was used as a model reaction and a radical chain reaction mechanism was revealed by the DFT method.

Graphical abstract: Oxidation of benzylic compounds by gold nanowires at 1 atm O2

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Publication details

The article was received on 25 May 2010, accepted on 11 Oct 2010 and first published on 19 Nov 2010


Article type: Communication
DOI: 10.1039/C0CC01568G
Citation: Chem. Commun., 2011,47, 1303-1305
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    Oxidation of benzylic compounds by gold nanowires at 1 atm O2

    L. Hu, X. Cao, J. Yang, M. Li, H. Hong, Q. Xu, J. Ge, L. Wang, J. Lu, L. Chen and H. Gu, Chem. Commun., 2011, 47, 1303
    DOI: 10.1039/C0CC01568G

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