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Issue 1, 2011
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Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation

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Abstract

A cyclohexadiene ligand prepared by microbial arene 1,2-dihydroxylation undergoes spontaneous rearrangement upon complexation to tricarbonyliron(0). Subsequent iron removal affords a novel route to formal arene 2,3-dihydroxylation products enantiomeric to those obtainable by direct microbial arene oxidation.

Graphical abstract: Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation

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Publication details

The article was received on 28 Apr 2010, accepted on 23 Jul 2010 and first published on 20 Aug 2010


Article type: Communication
DOI: 10.1039/C0CC01169J
Citation: Chem. Commun., 2011,47, 215-217
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    Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation

    M. A. Khan, J. P. Lowe, A. L. Johnson, A. J. W. Stewart and S. E. Lewis, Chem. Commun., 2011, 47, 215
    DOI: 10.1039/C0CC01169J

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