Multidimensional structures made by gold nanoparticles with shape-adaptive grafting layers

Michal Wojcik; Milena Kolpaczynska; Damian Pociecha; Jozef Mieczkowski; Ewa Gorecka

doi:10.1039/C0SM00539H

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Soft Matter

Issue 21, 2010

Where physics meets chemistry meets biology for fundamental soft matter research.

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Multidimensional structures made by gold nanoparticles with shape-adaptive grafting layers

Michal Wojcik,^a Milena Kolpaczynska,^a Damian Pociecha,^a Jozef Mieczkowski^a and Ewa Gorecka*^a

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University of Warsaw, Department of Chemistry, ul. Zwirki i Wigury 101, Warsaw, Poland
E-mail: gorecka@chem.uw.edu.pl

Soft Matter, 2010,6, 5397-5400

DOI: 10.1039/C0SM00539H
Received 16 Jun 2010, Accepted 06 Aug 2010
First published online 09 Sep 2010

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Abstract
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The ability of gold nanoparticles grafted with soft, adaptive organic layers made of two types of thiol molecules, n-alkyl and mesogenic ones, to form spontaneously long-range positionally ordered structures is shown. It was found that molecular structure of mesogenic thiols as well as the n-alkyl thiols can affect the type of the phase. A number of structures, smectic, undulated smectic and columnar phases, were obtained thanks to the self-segregation of mesogenic and simple n-alkyl ligands at the nanoparticle surface.

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Synthesis and chemical characterization of obtained materials, and detailed description of experimental methods used for structure studies.
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Michal Wojcik
Milena Kolpaczynska
Damian Pociecha
Jozef Mieczkowski
Ewa Gorecka

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