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Issue 18, 2010
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Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)2/HPMoV/O2 system

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Abstract

A facile direct synthesis of cinnamonitriles from acrylonitriles and benzenes is successfully achieved by using Pd(OAc)2/HPMoV/O2 catalyst system via the direct C–H bond activation of benzenes using molecular oxygen as a terminal oxidant.

Graphical abstract: Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)2/HPMoV/O2 system

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Publication details

The article was received on 27 May 2010, accepted on 07 Jul 2010 and first published on 23 Jul 2010


Article type: Communication
DOI: 10.1039/C0OB00176G
Citation: Org. Biomol. Chem., 2010,8, 4071-4073
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    Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)2/HPMoV/O2 system

    Y. Obora, Y. Okabe and Y. Ishii, Org. Biomol. Chem., 2010, 8, 4071
    DOI: 10.1039/C0OB00176G

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