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Issue 13, 2010
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Efforts toward rapid construction of the cortistatin A carbocyclic core via enyne-ene metathesis

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Abstract

Our efforts toward the construction of the carbocylic core of cortistatin A via an enyne-ene metathesis are disclosed. Interestingly, an attempted SN2 inversion of a secondary mesylate in our five-membered D-ring piece gave a product with retention of stereochemistry.

Graphical abstract: Efforts toward rapid construction of the cortistatin A carbocyclic core via enyne-ene metathesis

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Publication details

The article was received on 17 Mar 2010, accepted on 04 May 2010 and first published on 24 May 2010


Article type: Communication
DOI: 10.1039/C004275G
Citation: Org. Biomol. Chem., 2010,8, 2915-2917
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    Efforts toward rapid construction of the cortistatin A carbocyclic core via enyne-ene metathesis

    C. Baumgartner, S. Ma, Q. Liu and B. M. Stoltz, Org. Biomol. Chem., 2010, 8, 2915
    DOI: 10.1039/C004275G

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