A short, chemoenzymatic route to chiral β-aryl-γ-amino acids using reductases from anaerobic bacteria

Anna Fryszkowska; Karl Fisher; John M. Gardiner; Gill M. Stephens

doi:10.1039/B919526B

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Organic & Biomolecular Chemistry

Issue 3, 2010

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A short, chemoenzymatic route to chiral β-aryl-γ-amino acids using reductases from anaerobic bacteria

Anna Fryszkowska , Karl Fisher , John M. Gardiner and Gill M. Stephens

Org. Biomol. Chem., 2010, 8, 533-535

DOI: 10.1039/B919526B
Received 18 Sep 2009, Accepted 28 Oct 2009
First published on the web 10 Nov 2009
This article is part of the collection: Biocatalysis

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Abstract
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A short chemoenzymatic synthesis of β-aryl-γ-aminobutyric acids has been developed, based on a highly enantioselective biocatalytic reduction of β-aryl-β-cyano-α,β-unsaturated carboxylic acids.

Supplementary Info

Experimental details, anaerobic methodology, cell growth, circular dichroism and full characterisation data and copies of the ¹H and ¹³C NMR spectra for the prepared compounds
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Organic & Biomolecular Chemistry

A short, chemoenzymatic route to chiral β-aryl-γ-amino acids using reductases from anaerobic bacteria

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