Small molecule induced control in duplex and triplex DNA-directed chemical reactions

Mikkel F. Jacobsen; Jens B. Ravnsbæk; Kurt V. Gothelf

doi:10.1039/B919387A

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Organic & Biomolecular Chemistry

Issue 1, 2010

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Small molecule induced control in duplex and triplex DNA-directed chemical reactions

Mikkel F. Jacobsen , Jens B. Ravnsbæk and Kurt V. Gothelf

Org. Biomol. Chem., 2010, 8, 50-52

DOI: 10.1039/B919387A
Received 17 Sep 2009, Accepted 27 Oct 2009
First published on the web 09 Nov 2009

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Abstract
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Triplex DNA binders can effectively control copper-catalysed alkyne–azide click reactions in DNA architecture, such that either duplex or triplex DNA directed reactions of terminally attached azides and alkynes occur, in the absence or presence of triplex DNA binder, respectively.

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Experimental procedures, MALDI-TOF and RP-HPLC data, andspectral data for all new compounds
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Organic & Biomolecular Chemistry

Small molecule induced control in duplex and triplex DNA-directed chemical reactions

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