Facile P,N-heterocycle synthesis via tandem aminomethylation–cyclization of H-phosphinate building blocks

Clémence Queffélec; Jean-Luc Montchamp

doi:10.1039/B917428A

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Organic & Biomolecular Chemistry

Issue 1, 2010

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Facile P,N-heterocycle synthesis via tandem aminomethylation–cyclization of H-phosphinate building blocks

Clémence Queffélec and Jean-Luc Montchamp

Org. Biomol. Chem., 2010, 8, 267-273

DOI: 10.1039/B917428A
Received 24 Aug 2009, Accepted 25 Sep 2009
First published on the web 05 Nov 2009

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Various heterocycles containing phosphorus and nitrogen are easily synthesized from readily available H-phosphinate building blocks. Aminomethylation of these H-phosphinates is followed by in situ cyclization through substitution or cross-coupling to produce novel heterocycles in moderate to good yields.

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Organic & Biomolecular Chemistry

Facile P,N-heterocycle synthesis via tandem aminomethylation–cyclization of H-phosphinate building blocks

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