Effect of the allylic substituents on ring closing metathesis: the total synthesis of stagonolide B and 4-epi-stagonolide B

Awadut G. Giri; Mohabul A. Mondal; Vedavati G. Puranik; Chepuri V. Ramana

doi:10.1039/B916198H

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Organic & Biomolecular Chemistry

Issue 2, 2010

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Effect of the allylic substituents on ring closing metathesis: the total synthesis of stagonolide B and 4-epi-stagonolide B

Awadut G. Giri , Mohabul A. Mondal , Vedavati G. Puranik and Chepuri V. Ramana

Org. Biomol. Chem., 2010, 8, 398-406

DOI: 10.1039/B916198H
Received 06 Aug 2009, Accepted 29 Sep 2009
First published on the web 29 Oct 2009

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The total syntheses of stagonolide B and its 4-epimer were carried out to probe into how the relative stereochemistry of allylic hydroxy groups and their protecting groups influence the efficiency of the ring closing metathesis.

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Organic & Biomolecular Chemistry

Effect of the allylic substituents on ring closing metathesis: the total synthesis of stagonolide B and 4-epi-stagonolide B

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