Issue 11, 2010
From the journal:

New Journal of Chemistry

A two-fold interpenetrated (3,6)-connected metal–organic framework with rutile topology showing a large solvent cavity†‡

Xiaokai Song,§ab   Yang Zou,§b   Xinfang Liu,ab   Minhak Oha  and  Myoung Soo Lah*a  

* Corresponding authors

a Interdisciplinary School of Green Energy, Ulsan National Institute of Science & Technology, Ulsan, Korea
E-mail: mslah@unist.ac.kr
Fax: +82 522172019
Tel: +82 522172931

b Department of Chemistry and Applied Chemistry, Hanyang University, Ansan, Kyunggi-do, Korea

Abstract

A two-fold interpenetrated metal–organic framework (MOF), [(Zn4O)2L4(DMF)2(H2O)3], was prepared using the tritopic ligand 4,4′,4′′-[1,3,5-benzenetriyltris(carbonylimino)]trisbenzoic acid (H3L) and zinc nitrate. The MOF, based on the hexatopic tetranuclear Zn4O(COO)6 secondary building unit, has a (3,6)-connected network with an rtl topology and a large solvent cavity.

Graphical abstract: A two-fold interpenetrated (3,6)-connected metal–organic framework with rutile topology showing a large solvent cavity

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Article information

DOI
https://doi.org/10.1039/C0NJ00272K
Article type
Letter
Submitted
13 Apr 2010
Accepted
18 Jun 2010
First published
26 Jul 2010

New J. Chem., 2010,34, 2396-2399

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A two-fold interpenetrated (3,6)-connected metal–organic framework with rutile topology showing a large solvent cavity

X. Song, Y. Zou, X. Liu, M. Oh and M. S. Lah, New J. Chem., 2010, 34, 2396 DOI: 10.1039/C0NJ00272K

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