Jump to main content
Jump to site search

Issue 11, 2010
Previous Article Next Article

Cytosine modules in quadruple hydrogen bonded arrays

Author affiliations


Cytosine modules have been investigated for applications in supramolecular quadruple hydrogen bonded arrays. Notably, the importance of the C-5–H in the formation of unfolded and folded arrays by substitution to C-5–F was established. In addition, the incorporation of different alkyl chain lengths at N-1 and N-9 indicated that longer alkyl chains give rise to more of the unfolded rotamer, with the chain length and degree of unsaturation at N-1 having the major effect. Methyl cytosine modules were also able to readily form hetero-associated Upy–UCyt dimers as efficiently as the hexyl cytosine modules and a polyadipate telechelic polymer was used to prepare cytosine polymers.

Graphical abstract: Cytosine modules in quadruple hydrogen bonded arrays

Back to tab navigation

Publication details

The article was received on 15 Mar 2010, accepted on 05 Jun 2010 and first published on 03 Aug 2010

Article type: Paper
DOI: 10.1039/C0NJ00197J
Citation: New J. Chem., 2010,34, 2634-2642
  •   Request permissions

    Cytosine modules in quadruple hydrogen bonded arrays

    E. Greco, A. E. Aliev, V. G. H. Lafitte, K. Bala, D. Duncan, L. Pilon, P. Golding and H. C. Hailes, New J. Chem., 2010, 34, 2634
    DOI: 10.1039/C0NJ00197J

Search articles by author