Issue 3, 2010
From the journal:

New Journal of Chemistry

Stereochemistry effect of dicyclohexano-18-crown-6 on zinc isotope separation

Yi Lin,a   Jeff Espinas,a   Stéphane Pellet-Rostaing,*ab   Alain Favre-Réguillona  and  Marc Lemaire*a  

* Corresponding authors

a ICBMS, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, Laboratoire de Catalyse et Synthèse Organique, Université de Lyon, 43 boulevard du 11 novembre 1918, Villeurbanne, France

b ICSM, Institut de Chimie Séparative de Marcoule, Laboratoire de Tri Ionique par des Systèmes Auto-assemblés, Marcoule, France

Abstract

Zinc isotope fractionation is reported with the pure cis-syn-cis and cis-anti-cis stereoisomers of dicyclohexano-18-crown-6. These structures contribute differently to the enrichment of the Zn isotopes, and the best fractionation was obtained with the cis-syn-cis derivative.

Graphical abstract: Stereochemistry effect of dicyclohexano-18-crown-6 on zinc isotope separation

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Article information

DOI
https://doi.org/10.1039/B9NJ00417C
Article type
Letter
Submitted
19 Aug 2009
Accepted
10 Dec 2009
First published
19 Jan 2010

New J. Chem., 2010,34, 388-390

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Stereochemistry effect of dicyclohexano-18-crown-6 on zinc isotope separation

Y. Lin, J. Espinas, S. Pellet-Rostaing, A. Favre-Réguillon and M. Lemaire, New J. Chem., 2010, 34, 388 DOI: 10.1039/B9NJ00417C

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