Issue 12, 2010
From the journal:

New Journal of Chemistry

Luminescent liquid crystal materials based on unsymmetrical boron difluoride β-diketonate adducts†

Ignacio Sánchez,a   María José Mayoral,a   Paloma Ovejero,a   José Antonio Campo,a   José Vicente Heras,a   Mercedes Cano*a  and  Carlos Lodeirob  

* Corresponding authors

a Departamento de Química Inorgánica I, Facultad de Ciencias Químicas, Universidad Complutens de Madrid, Madrid, Spain
E-mail: mmcano@quim.ucm.es
Fax: +34 91394 4352
Tel: +34 91394 4340

b Grupo BIOSCOPE, Departamento de Química-Física, Facultade de Ciencias, Campus de Ourense, Universidade de Vigo, Ourense, Spain
E-mail: clodeiro@uvigo.es
Fax: +34 98838 7001
Tel: +34 98836 8894

Abstract

A strategic design based on the use of asymmetrically 1,3-alkyloxyphenyl substituted β-diketonate ligands towards the BF2 group allowed us to find unsymmetrical compounds that, in addition to a high photoluminescent quantum yield, possess a liquid crystal behaviour, which is related to the presence of the banana-shaped liquid crystal mesophases B1.

Graphical abstract: Luminescent liquid crystal materials based on unsymmetrical boron difluoride β-diketonate adducts

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Article information

DOI
https://doi.org/10.1039/C0NJ00503G
Article type
Paper
Submitted
30 Jun 2010
Accepted
24 Aug 2010
First published
04 Oct 2010

New J. Chem., 2010,34, 2937-2942

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Luminescent liquid crystal materials based on unsymmetrical boron difluoride β-diketonate adducts

I. Sánchez, M. J. Mayoral, P. Ovejero, J. A. Campo, J. V. Heras, M. Cano and C. Lodeiro, New J. Chem., 2010, 34, 2937 DOI: 10.1039/C0NJ00503G

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