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Issue 3, 2010
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Iron-coated TiO2 nanotubes and their photocatalytic performance

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Abstract

Iron-coated TiO2 nanotubes are successfully synthesized by treating hydrogen titanate nanotubes with Fe(OH)3 sol. The products are characterized with transmission electron microscopy, atomic absorption spectrometer, X-ray diffraction, Raman spectroscopy, UV-visible absorption spectroscopy and nitrogen adsorption. The photocatalytic performance is evaluated by the photocatalytic degradation rates of methyl orange in aqueous solution under UV-vis light irradiation. The effects of the calcination temperature, concentration of Fe(OH)3 sol and pH value of solution on the photocatalytic performance of iron-coated nanotubes are investigated. The results reveal that the iron-coated nanotubes exhibit better thermal stability and photocatalytic performance than their precursors. The iron-coated nanotubes can keep the nanotubular structure when calcined at 400 °C, and the specific surface area does not decrease sharply. We also discover that the pH of the solution has an obvious influence on the photocatalytic activity of iron-coated nanotubes. When the pH is about 2.4, the maximum photodegradation rate appears; moreover, the recycled catalyst still shows good photodegradation activity.

Graphical abstract: Iron-coated TiO2 nanotubes and their photocatalytic performance

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Publication details

The article was received on 27 Apr 2009, accepted on 22 Oct 2009 and first published on 23 Nov 2009


Article type: Paper
DOI: 10.1039/B908226C
Citation: J. Mater. Chem., 2010,20, 603-610
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    Iron-coated TiO2 nanotubes and their photocatalytic performance

    H. An, J. Li, J. Zhou, K. Li, B. Zhu and W. Huang, J. Mater. Chem., 2010, 20, 603
    DOI: 10.1039/B908226C

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