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Issue 48, 2010
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Self-induced “electroclick” immobilization of a copper complex onto self-assembled monolayers on a gold electrode

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Abstract

We report the self-induced “electroclick” immobilization of the [CuII(6-ethynyl-TMPA)(H2O)]2+ complex, by its simple electro-reduction, onto a mixed azidoundodecane-/decane-thiol modified gold electrode. The redox response of the grafted [CuII/I(TMPA)] at the modified electrode is fully reversible indicating no Cu coordination change and a fast electron transfer.

Graphical abstract: Self-induced “electroclick” immobilization of a copper complex onto self-assembled monolayers on a gold electrode

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Publication details

The article was received on 24 Aug 2010, accepted on 14 Oct 2010 and first published on 03 Nov 2010


Article type: Communication
DOI: 10.1039/C0DT01093F
Citation: Dalton Trans., 2010,39, 11516-11518
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    Self-induced “electroclick” immobilization of a copper complex onto self-assembled monolayers on a gold electrode

    A. Gomila, N. Le Poul, N. Cosquer, J. Kerbaol, J. Noël, M. T. Reddy, I. Jabin, O. Reinaud, F. Conan and Y. Le Mest, Dalton Trans., 2010, 39, 11516
    DOI: 10.1039/C0DT01093F

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