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Issue 45, 2010
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A tetranuclear cobalt(II) chain with slow magnetization relaxation

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Abstract

A solvothermally derived tetranuclear cobalt(II) complex, [Co4(phen)4Cl8] (phen = phenanthroline), featuring a zig-zag backbone of {Co(μ2-Cl)2Co} planes, exhibits ferromagnetic exchange and slow relaxation of the magnetization and represents the first Co SMM with a linear core structure.

Graphical abstract: A tetranuclear cobalt(ii) chain with slow magnetization relaxation

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Publication details

The article was received on 30 Jul 2010, accepted on 22 Sep 2010 and first published on 18 Oct 2010


Article type: Communication
DOI: 10.1039/C0DT00935K
Citation: Dalton Trans., 2010,39, 10827-10829
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    A tetranuclear cobalt(II) chain with slow magnetization relaxation

    Y. Zheng, M. Speldrich, H. Schilder, X. Chen and P. Kögerler, Dalton Trans., 2010, 39, 10827
    DOI: 10.1039/C0DT00935K

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