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Issue 41, 2010
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Synthesis and comparative anion binding profiles of two di-aqua Eu(III) complexes

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Abstract

Two di-aqua Eu(III) complexes of heptadentate ligands are reported that show differing reactivity profiles towards various anions; a cationic complex with two azaxanthone moieties exhibits pronounced selectivity towards bicarbonate with an affinity constant, logK = 2.65 (295 K, 0.1 M NaCl).

Graphical abstract: Synthesis and comparative anion binding profiles of two di-aqua Eu(iii) complexes

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Publication details

The article was received on 02 Jul 2010, accepted on 26 Aug 2010 and first published on 17 Sep 2010


Article type: Paper
DOI: 10.1039/C0DT00773K
Citation: Dalton Trans., 2010,39, 9897-9903
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    Synthesis and comparative anion binding profiles of two di-aqua Eu(III) complexes

    D. Imperio, G. B. Giovenzana, G. Law, D. Parker and J. W. Walton, Dalton Trans., 2010, 39, 9897
    DOI: 10.1039/C0DT00773K

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