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Issue 38, 2010
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Long-range ferromagnetic ordering in a 3D CuII-tetracarboxylate framework assisted by an unprecedented bidentate μ2-O1,N4 hypoxanthine nucleobase

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Abstract

The first hypoxanthine (hypH)-assisted 3D CuII-tetracarboxylate framework, {[Cu2(hypH)0.5(H2O)0.5(btec)]·1.5H2O}n (btec = 1,2,4,5-benzenetetracarboxylate), was synthesized and exhibits long-range ferromagnetic ordering below 4.5 K, which opens a new window for the applications of nucleobase-based MOFs as magnetic materials.

Graphical abstract: Long-range ferromagnetic ordering in a 3D CuII-tetracarboxylate framework assisted by an unprecedented bidentate μ2-O1,N4 hypoxanthine nucleobase

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Publication details

The article was received on 23 Jun 2010, accepted on 25 Jun 2010 and first published on 31 Aug 2010


Article type: Communication
DOI: 10.1039/C0DT00717J
Citation: Dalton Trans., 2010,39, 8868-8871
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    Long-range ferromagnetic ordering in a 3D CuII-tetracarboxylate framework assisted by an unprecedented bidentate μ2-O1,N4 hypoxanthine nucleobase

    E. Yang, Z. Liu, Z. Liu, L. Zhao and X. Zhao, Dalton Trans., 2010, 39, 8868
    DOI: 10.1039/C0DT00717J

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