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Issue 37, 2010
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Speciation of heptavalent technetium in sulfuric acid: structural and spectroscopic studies

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Abstract

The speciation of Tc(VII) was studied in 12 M H2SO4 by NMR, UV-visible and XAFS spectroscopy. Experimental results and density functional calculations show the formation of TcO3(OH)(H2O)2.

Graphical abstract: Speciation of heptavalent technetium in sulfuric acid: structural and spectroscopic studies

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Publication details

The article was received on 22 Jun 2010, accepted on 03 Aug 2010 and first published on 23 Aug 2010


Article type: Communication
DOI: 10.1039/C0DT00695E
Citation: Dalton Trans., 2010,39, 8616-8619
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    Speciation of heptavalent technetium in sulfuric acid: structural and spectroscopic studies

    F. Poineau, P. F. Weck, K. German, A. Maruk, G. Kirakosyan, W. Lukens, D. B. Rego, A. P. Sattelberger and K. R. Czerwinski, Dalton Trans., 2010, 39, 8616
    DOI: 10.1039/C0DT00695E

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