Unexpected transformation of a diamagnetic Mo3(μ3-S)(μ-S)3 to a paramagnetic Mo3(μ3-S)2(μ-S)3cluster core by reaction of [Mo3S4(dppe)3Br3]PF6 with tBuSNa†‡
Abstract
The electron precise
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* Corresponding authors
a
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of RAS, Ak. Lavrentieva Av., 3, Novosibirsk, Russian Federation
E-mail:
konch@niic.nsc.ru
Fax: (+7) 383 330 9489
Tel: (+7) 383 316 5845
b Novosibirsk State University, Pirogova St., 2, Novosibirsk, Russian Federation
c
Departament de Química Física i Analítica, Universitat Jaume I, Av. Sos Baynat s/n, Castelló, Spain
E-mail:
Rosa.Llusar@qfa.uji.es
Fax: (+34) 964728066
Tel: (+34) 964728086
The electron precise
P. A. Petrov, A. V. Virovets, A. Alberola, R. Llusar and S. N. Konchenko, Dalton Trans., 2010, 39, 8875 DOI: 10.1039/C0DT00675K
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