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Issue 32, 2010
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Redox-active ferrocene-modified Cowpea mosaic virus nanoparticles

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Abstract

A naturally occurring nanoparticle, the plant virus Cowpea mosaic virus, can be decorated with ferrocene derivatives, of various linker lengths with amine and carboxylate groups, on the external surface using a range of conjugation strategies. The multiple, organometallic, redox-active ferrocene moieties on the outer surface of the virus are electrochemically independent with reduction potentials that span a potential window of 0.16 V that are dependent on the site of modification and the nature of the ferrocene derivative. The number of ferrocenes coupled to each virus ranges from about 100 to 240 depending upon the conjugation site and the linker length and these redox active units can provide multielectron reservoirs.

Graphical abstract: Redox-active ferrocene-modified Cowpea mosaic virus nanoparticles

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Publication details

The article was received on 18 May 2010, accepted on 11 Jun 2010 and first published on 09 Jul 2010


Article type: Paper
DOI: 10.1039/C0DT00495B
Citation: Dalton Trans., 2010,39, 7569-7574
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    Redox-active ferrocene-modified Cowpea mosaic virus nanoparticles

    A. A. A. Aljabali, J. E. Barclay, J. N. Butt, G. P. Lomonossoff and D. J. Evans, Dalton Trans., 2010, 39, 7569
    DOI: 10.1039/C0DT00495B

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