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Issue 40, 2010
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Asymmetric general base catalysis of the phospho-aldol reaction via dimeric aluminium hydroxides

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Abstract

Dimeric aluminium hydroxide complexes containing the (R,R)-N,N′-bis(2′-hydroxy-3′-organobenzyl)-trans-1,2-diaminocyclohexane ligand backbone effect catalysis of the phospho-aldol reaction under ambient, aerobic conditions at catalyst loadings of 0.5 mol% to afford enantioselectivities of ca. 65%.

Graphical abstract: Asymmetric general base catalysis of the phospho-aldol reaction via dimeric aluminium hydroxides

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The article was received on 11 May 2010, accepted on 05 Aug 2010 and first published on 16 Sep 2010


Article type: Communication
DOI: 10.1039/C0DT00459F
Citation: Dalton Trans., 2010,39, 9472-9475
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    Asymmetric general base catalysis of the phospho-aldol reaction via dimeric aluminium hydroxides

    A. C. Gledhill, N. E. Cosgrove, T. D. Nixon, C. A. Kilner, J. Fisher and T. P. Kee, Dalton Trans., 2010, 39, 9472
    DOI: 10.1039/C0DT00459F

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