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Issue 39, 2010
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Synthesis and structures of (dialkylsilylene)bis(phosphine)-nickel, palladium, and platinum complexes and (η6-arene)(dialkylsilylene)nickel complexes

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Abstract

A series of dialkylsilylene-group 10 metal complexes (RH2Si)(Me3P)2M (M = Ni, Pd, Pt, RH2 = 1,1,4,4-tetrakis(trimethylsilyl)butane-1,4-diyl) and novel (η6-arene)(dialkylsilylene)nickel complexes (η6-arene)(RH2Si)Ni were synthesized and characterized by NMR spectroscopy and X-ray analysis. The perpendicular geometry around the Si–M bond and the short Si–M distances of (RH2Si)(Me3P)2M complexes indicate the significant back donation from the metal to the silylene ligand.

Graphical abstract: Synthesis and structures of (dialkylsilylene)bis(phosphine)-nickel, palladium, and platinum complexes and (η6-arene)(dialkylsilylene)nickel complexes

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Publication details

The article was received on 03 May 2010, accepted on 27 Jul 2010 and first published on 31 Aug 2010


Article type: Paper
DOI: 10.1039/C0DT00415D
Citation: Dalton Trans., 2010,39, 9414-9420
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    Synthesis and structures of (dialkylsilylene)bis(phosphine)-nickel, palladium, and platinum complexes and (η6-arene)(dialkylsilylene)nickel complexes

    C. Watanabe, Y. Inagawa, T. Iwamoto and M. Kira, Dalton Trans., 2010, 39, 9414
    DOI: 10.1039/C0DT00415D

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