Issue 41, 2010
From the journal:

Dalton Transactions

“Super hybrid tridentate ligands”: 4-substituted-2-(1-butyl-1H-1,2,3-triazol-4-yl)-6-(1H-pyrazol-1-yl)pyridine ligands coordinated to Fe(ii) ions display above room temperature spin transitions†

Naisa Chandrasekhara  and  Rajadurai Chandrasekar*a  

* Corresponding authors

a School of Chemistry, University of Hyderabad, Prof. C. R. Rao Road, Gachi Bowli, Hyderabad, India
E-mail: rcsc@uohyd.ernet.in, chandrasekar100@yahoo.com
Fax: +91(40)23134824
Tel: +91(40)23134824

Abstract

A series of novel “super hybrid tridentate ligands” based on (2-(1-butyl-1H-1,2,3-triazol-4-yl)-6-(1H-pyrazol-1-yl)pyridine (tpp) derivatives were synthesized. Their Fe(II) complexes display around (T½ = 287 K) and above room temperature (T½ ≫ 375 K) spin transition temperatures.

Graphical abstract: “Super hybrid tridentate ligands”: 4-substituted-2-(1-butyl-1H-1,2,3-triazol-4-yl)-6-(1H-pyrazol-1-yl)pyridine ligands coordinated to Fe(ii) ions display above room temperature spin transitions

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Article information

DOI
https://doi.org/10.1039/C0DT00373E
Article type
Paper
Submitted
27 Apr 2010
Accepted
27 Jul 2010
First published
17 Sep 2010

Dalton Trans., 2010,39, 9872-9878

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“Super hybrid tridentate ligands”: 4-substituted-2-(1-butyl-1H-1,2,3-triazol-4-yl)-6-(1H-pyrazol-1-yl)pyridine ligands coordinated to Fe(II) ions display above room temperature spin transitions

N. Chandrasekhar and R. Chandrasekar, Dalton Trans., 2010, 39, 9872 DOI: 10.1039/C0DT00373E

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