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School of Chemistry, University of St Andrews, Purdie Building, North Haugh, St Andrews, UK
E-mail: paw2@st-andrews.ac.uk
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b
European Synchrotron Radiation Facility, Grenoble, France
Dalton Trans., 2010,39, 6389-6391
DOI:
10.1039/C0DT00233J
Received
31 Mar 2010,
Accepted
04 Jun 2010
First published online
21 Jun 2010
Crystallisation of yttrium and other trivalent metal cations of similar radius with racemic N,N′-2-methylpiperazinebis(methylene phosphonic acid) gives a small pore bisphosphonate metal–organic framework solid displaying coordinative and hydrogen bonding and permanent porosity.
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